Guide to Spectroscopic Identification of Organic Compounds is a practical "how-to" book with a general problem-solving algorithm for determining the structure of a molecule from complementary spectra or spectral data obtained from MS, IR, NMR, or UV spectrophotometers. Representative compounds are analyzed and examples are solved. Solutions are eclectic, ranging from simple and straightforward to complex. A picture of the relationship of structure to physical properties, as well as to spectral features, is provided. Compounds and their derivatives, structural isomers, straight-chain molecules, and aromatics illustrate predominant features exhibited by different functional groups. Practice problems are also included.
Guide to Spectroscopic Identification of Organic Compounds is a helpful and convenient tool for the analyst in interpreting organic spectra. It may serve as a companion to any organic textbook or as a spectroscopy reference; its size allows practitioners to carry it along when other tools might be cumbersome or expensive.
The General Problem-Solving Approach
General Problem-Solving Algorithm
Helpful Hints
Sample Compounds
Spectroscopic Aids
Spectroscopic Methods
Sample Handling
Units in Spectroscopy
Useful Equations
Predominant Features in the Spectra
Recognition of the Molecular Ion
Intensities of Remarkable Heteroatom Isotope Peaks
Molecular Formula Compilation Table
Levels of Unsaturation (LU)
Diagnostic Fragment Ions in the Mass Spectrum
Diagnostic IR Absorptions Frequencies
Wavelength to Wave Number Conversion Table
Comparison of Information from 1H NMR and 13C NMR
Approximate Chemical Shifts in 1H NMR
Integration of 1H NMR
Approximate Chemical Shifts in 13C NMR
UV Absorptions of Chromophores
Glossary
Representative Compounds
Practice Problems
Appendices
Bibliography
Field Names
Abbreviations
Indices
CAS Registry Number Index
Name/Synonym Index
Answers to Practice Problems