Catalysis of Organic Reactions
Purchasing Options
Features
Summary
This volume compiles 63 peer-reviewed scientific papers documenting the latest developments in the application of homogeneous, heterogeneous, and immobilized homogenous catalysts used in organic synthesis. Catalysis of Organic Reactions consists of primary research articles accompanied by experimental sections that emphasize chemical processes with actual and potential applications in industry. Each chapter represents current and outstanding research by recognized leaders in the field.
Organized into five major symposia, topics include selective homogeneous and heterogeneous catalysis for the synthesis of fine chemical and pharmaceuticals, solid acid catalysis, selective oxidation, amination, chiral catalysis, combinatorial technologies, nanoparticles, environmentally friendly catalysis, and more. The collection also presents the award-winning research of Jean Lessard, concerning the scope and limitations of electrocatalytic hydrogenation of organic compounds at Raney Metal Electrodes, and Richard Larock, relating to palladium-catalyzed annulation and migration reactions.
These proceedings are of interest to the chemical scientists and engineers whose special interest is to apply homogenous and heterogeneous catalysts in organic synthesis of pharmaceutical, fine, and commodity chemicals.
Table of Contents
Preface
Symposium on Catalytic Hydrogenation
Hydrogenation on Raney-Type Catalysts
2004 Murray Raney Lecture, Electrocatalytic Hydrogenation of Organic Compounds at Raney Metal Electrodes: Scope and Limitations
Low Pressure Slurry Hydrogenation Process for the Production of Dimethylaminopropylamine Using Sponge Nickel Catalyst
The Conversion of Ethanolamine to Glycine Salt Over Skeletal Copper Catalysts
Hydrogenation Catalysis in a Nylon Recycle Process
Hydrogenation of Dodecanenitrile Over Raney Type and Supported Group VIII. Effect of Metal on Selectivity
Anchored and Supported Hydrogenation Catalysts
Highly Efficient Catalysts Supported on Carbon Cloths for Carbohydrate Hydrogenation
Anchored Wilkinson's Catalyst
Carbon Supported Anchored Homogeneous Catalyst
Catalytic Hydrogenation of Cinnamaldehyde on Pt/Carbon Catalysts: The Effects of Metal Location, and Dispersion on Activity and Selectivity
Para-substituted Aniline Hydrogenation Over Rhodium Catalysts: Metal Particle Size and Catalyst Pore Size Effects
Reductive Alkylation During Nitrobenzene Hydrogenation Over Copper/Silica
Hydrogenolysis of Butyl Acetate to Butanol Over Naphtha Reforming Type Catalysts in Conventional and High Throughput Slurry Phase Reactors
New Ways for the Full Hydrogenation of Quinoline in Mild Conditions
Some Recent Developments of Heterogeneous Hydrogenation Catalysts for Organic Synthesis
Hydrogenation of Interesting Substrates and Renewable Sources
Hydrogenation of Nitrile Butadiene Rubber Catalyzed by [Ir(COD)py(PCy3)]PF6
Catalytic Hydrogenation and Hydrogenolysis of Lignin Model Compounds Using In-Situ, Water-Soluble Ru/P(CH2OH)3 Systems
Catalytic Preparation of Pyrrolidones from Renewable Resources
Hydrogenation of Glutamic Acid to Value Added Products
Catalytic Hydrogenolysis of 5-Carbon Sugar Alcohols
Symposium on Novel Concepts and Approaches to Catalysis of Organic Reactions
Featured Technology Area: Combinatorial and Parallel Methods in Catalyst Design, Optimization and Utilization
Combinatorial Approaches for New Catalysts Discovery: The First Homogeneous Catalysts Derived from Combinatorial Technologies for a Variety of Cross-Coupling Reactions
High Throughput Experiments in Design and Optimization of Catalytic Package for Direct Diphenylcarbonate Synthesis
Rapid Optimization of Hydrogenation Process Variables by Combining Experimental Design and Parallel Reactors
Design and Parallel synthesis of New Oxidative Dehydrogenation Catalysts
Nanocluster-based Cross-coupling Catalysts: A High-Throughput Approach
General papers
Do You Need A Transition Metal for Biaryl Synthesis?
Enzyme-like Acceleration in Catalytic Anti-Markovnikov Hydration of Alkynes to Aldehydes
An Enzyme-like Mechanism Involving Bifunctional Ru Catalysts
Activation of Dendrimer Encapsulated Pt Nanoparticles for Heterogeneous Catalysts
Avada-A New Green Process for the Production of Ethyl Acetate
A Catalytic Distillation Process for the One Step Synthesis of Methyl Isobutyl Ketone from Acetone: Liquid Phase Kinetics of the Hydrogenation of Mesityl Oxide
A Strategy for the Preparation of Isolated Organometallic Catalysts on Silica Supports - Towards Single-Site Solid Catalysts
Ring Opening of Naphthenes for Clean Diesel Fuel Production
The Use of Copper Catalysts in the Hydrogen Transfer Reduction of 4-Tert-butylcyclohexanone
The Effect of Ultrasound on the Isomerization versus Reduction Reaction Pathways in the Hydrogenation of 3-Buten-2-ol and 1,4-Pentadien-3-ol on Pd-Black
Lessons Learned, Batch Processing Scaleup from Laboratory to Plant
Symposium on Acid-Base Catalysis
Improved Solid-Acid Catalysis for Sustainable, High 2-Phenyl, LAB Production
Recent Advances in Thermally Stable Resins for Olefin Hydration
Enhancement of Regioselectivity in the Gas-phase Methylation of m-Cresol with Multifunctional Heterogeneous Catalysts
Hydroxymethylation of 2-Methoxyphenol with Formaldehyde to Yield Vanillic Alcohols: A Comparison Between Homogeneous and Heterogeneous Acid Catalysis
The Aldol Condensation of Acetone Over a CsOH/SiO2 Solid Base Catalyst
Solid Acid Catalysed Esterification of Amino Acids
One Pot Transformation of Geraniol into Citronellol and Menthol Over Cu/Al2O3
Investigation of Chlorine Substitution Effects in the Claisen-Schmidt Condensation of 2-hydroxyacetophenone with Chlorobenzaldehydes Over MgO
Symposium on Catalytic Oxidation
The Effect of Single Metal Variation in Mo-V-Nb-W/Al2O3 System on Propane Selective Oxidation
Partial Oxidation of Propylene Over Supported Rhodium Catalysts
The Effect of Promoters on the Platinum Group Metal Catalysed Selective Oxidation of Alcohols to Carbonyls or Acids
Synergistic Effect of Vanadium on the Activity of Titanium-Modified Silica Catalysts for Olefin Epoxidation
Aerobic Formaldehyde Oxidation Under Mild Conditions Mediated by Ce-Containing Polyoxometalates
Symposium on Catalysis in Organic Synthesis
General Papers
2004 Paul N. Rylander Award: Palladium-Catalyzed Annulation and Migration Reactions
New Palladium-catalysed Processes for the Synthesis of Selectively Substituted Aromatics
O-Acylphosphites: New and Promising Ligands for Isomerizing Hydroformylation
The Synthesis of Carbamate From the Reductive Carbonylation of Nitrobenzene Over Pd-based Catalysts
Microwave Synthesis in the Suzuki-Cross Coupling Reaction with Heterogenous Pd/C Catalysts
Deprotection
Improved Catalyst for the Removal of Carbobenzyloxy Protective Groups
The Effect of N-Containing Modifiers on the Deprotection of Carbobenzyloxy Protected Amino Acids
Selective Debenzylation in the Presence of Aromatic Chlorine on Pd/C Catalysts: Effects of Catalyst Types and Reaction Kinetics
Asymmetric Catalysis
A Comparison Between the Homogeneous and the Anchored Rhodium Skewphos Catalyst
Synthesis and Characterization of Dipeptido Phosphinite Ligands for Late Transition Metal Complexations and Their Potential as Catalysts
Enantioselective Hydrogenations of Exo- and Endocyclic C=C double Bond with Highly Mesoporous Carbon Supported Pd
Influence of Achiral Tertiary Amines on the Enantioselective Hydrogenation of a,b-diketones Over Cinchonidine-Pt/Al2O3 Catalyst
Enantioselective Hydrogenation of Diketones on Pt Supported Catalysts
Enantioselective Hydrogenation of a?b-Unsaturated Acids or Esters
The Effects of Pt/Al2O3 Structure and Stability on the O-Methyl-10,11-dihydrocinchonidine Modified Enantioselective Hydrogenation of Activated Ketones
Author Index
Keyword Index
Related Titles
