Handbook of Photochemistry, Third Edition

Handbook of Photochemistry, Third Edition

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ISBN 9780824723774
Cat# DK3093
 

Features

  • Features two introductory chapters familiarizing all audiences with the photochemistry of organic and inorganic molecules, written by world-renowned experts Josef Michl and Vincenzo Balzani
  • Expands and updates information on light sources, light filters, and chemical actinometry
  • Includes new tables of photophysical, quenching, and reduction potential data on metal complexes and organometallic compounds
  • Contains a new section that describes common problems in photoluminescence measurements and recommends effective solutions
  • Offers a wide and updated collection of references for each topic that allows readers to easily locate original articles
  • Summary

    Since the publication of the second edition of this handbook in 1993, the field of photochemical sciences has continued to expand across several disciplines including organic, inorganic, physical, analytical, and biological chemistries, and, most recently, nanosciences. Emphasizing the important role light-induced processes play in all of these fields, the Handbook of Photochemistry, Third Edition provides quick and convenient access to chemical and physical data that are crucial to photochemical investigations from the planning and experimentation phases to the interpretation of results.

    The third edition of the Handbook of Photochemistry offers detailed overviews of the photochemical processes that occur in organic molecules and transition metal complexes, written by leading experts around the world. The authors maintain the highly regarded organization of data from previous editions while updating and expanding its tables with data pertaining to hundreds of new compounds. The book now contains sections focusing on metal complexes and organometallic compounds, offering photophysical and quenching data as well as reduction potential values, a key factor in photochemical electron transfer processes. It also features new information on light sources and filters, chemical actinometry, solutions to common problems in photoluminescence measurements, and lab-friendly techniques pertaining to experimental UV/visible spectroscopy and irradiation methodologies.

    The Handbook of Photochemistry delivers an exhaustive, up-to-date collection of photophysical and electrochemical data on organic compounds and transition metal complexes. It represents an invaluable compilation of complementary data, background information, and references for students, researchers, and spectroscopists performing a vast assortment of photochemical experiments.

    Table of Contents

    Photophysics of Organic Molecules in Solution
    Introduction
    Electronic States
    Radiative Transitions
    Nonradiative Transitions
    Excited State Kinetics
    Acknowledgments
    Bibliography

    Transition Metal Complexes
    Electronic Structure
    Types of Excited States and Electronic Transitions
    Absorption and Emission Bands
    Jablonski Diagram
    Photochemical Reactivity
    Electrochemical Behavior
    Polynuclear Metal Complexes

    Photophysical Properties of Organic Compounds
    Photophysics of Organic Molecules in Solution
    Triplet-State Energies: Ordered
    Flash Photolysis: Designing Experiments
    Low-Temperature Photophysics of Organic Molecules
    Absorption and Luminescence Spectra of Organic Compounds

    ESR and ODMR Parameters of the Triplet State

    Photophysical Properties of Transition Metal Complexes
    Photophysical Parameters
    Absorption and Emission Spectra
    Abbreviations

    Rate Constants of Excited-State Quenching

    Ionization Energies, Electron Affinities, and Reduction Potentials
    Ionization Energies and Electron Affinities
    Reduction Potentials

    Bond Dissociation Energies

    Solvent Properties
    Donor Number

    Luminescence Spectroscopy Measurements
    Correction of Luminescence Intensity Measurements in Solution
    Fluorescence Quantum Yield Standards
    Phosphorescence Quantum Yield Standards
    Luminescence Lifetime Standards

    Light Sources and Filters
    Spectral Distribution of Photochemical Sources
    Transmission Characteristics of Light Filters and Glasses

    Chemical Actinometry
    Ferrioxalate Actinometer
    Photochromic Actinometers
    Reinecke's Salt Actinometer
    Uranyl Oxalate Actinometer
    Other Actinometers

    Miscellaneous
    Spin-Orbit Coupling
    Hammett ? Constants
    Fundamental Constants and Conversion Factors

    Index

    *References included in each chapter

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