1st Edition
Revival: Supercritical Fluid Technology (1991) Reviews in Modern Theory and Applications
In this volume, we have collected a series of reviews that cover both experimental and theoretical work geared toward the more exact requirements of current SFE applications. While we have artificially divided the volume into experimental and theoretical sections, natural overlaps will be apparent. Many of the papers on experimental and theoretical sections, natural overlaps will be apparent. Many of the papers on experimental technique contain discussions on equation of state correlations. Indeed, a good deal of the experimental work is intimately tied to a mathematical description of fluid mixtures.
The theoretical section presents reviews that cover the modern theory of critical phenomena, methods to correlate near critical experimental results and approaches to understanding the behavior of near critical fluids from microscopic theory. It is hoped that the scope of these reviews will provide the reader with the basis to further develop our understanding of the behavior of supercritical fluids.
PART 1: THEORY OF SUPERCRITICAL FLUIDS
Chaper 1
Thermodynamics of Solutions Near the Solvent's Critical Point
Chaper 2
Vapor-Liquid Equilibrium and the Modified Leung-Griffiths Model
Chaper 3
Molecular Analysis of Phase Equilibria in Supercritical Fluids
Chaper 4
Fluctuation Theory of Sueprcritical Solutions
Chaper 5
Application of Molecular Simulation to the Study of Supercritical Extraction
Chaper 6
Transport Properties of Supercritical Fluids and Fluid Mixtures
PART 2: EXPERIMENTAL WORK AND APPLICATIONS
Chapter 7
Thermophysical Property data for Supercritical Extraction Design
Chaper 8
Properties of Carbon Dioxide Rich Mixtures
Chapter 9
Thermal Conductivity and Difffusivity in Supercritical Fluids
Chapter 10
Mass Transfer in Supercritical Extraction from Solid Matrices
Chapter 11
Design and Control of Supercritical Processes: A Review
Chapter 12
Microemulsions in Near Critical and Supercritical Fluids
Chapter 13
Supercritical Fluid Extraction and Retrograde Condensation (SFE/RC)
Chapter 14
Supercritical Extraction in Environment Control
Chapter 15
Reactions In and With Supercritical Fluids
Chapter 16
A Summary of the Patent Literature of Supercritical Fluid Technology
Index
Biography
Dr. Thomas J. Bruno leads the Experimental Properties of Fluids Group of the Thermophysical Properties Division at NIST, Boulder. Dr. Bruno received his B.S. in chemistry from the Polytechnic Institute of Brooklyn (1976), and his M.S. and Ph.D. in physical chemistry from Georgetown University (1978, 1981). He served as a National Academy of Sciences-National Research Council postdoctoral associate at NIST, and was later appointed to the staff.