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A search for the enthalpy of formation of a particular compound can be a difficult task. So it is of great benefit that the values be collected together in one comprehensive compilation. Thermochemical Data and Structures of Organic Compounds presents approximately 3000 enthalpies of formation of organic compounds. There are many instances of large discrepancies reported for a particular compound. Thus, selection of the "best" value becomes a challenge for the person who is not a practicing thermochemist, but who only wishes to use the data. A critical evaluation of the values presented becomes desirable. This compilation presents about 3000 enthalpies of formation of organic compounds, all critically evaluated.
Table of Contents
Introduction 1 Selected Thermochemical Data and Comparisons with Calculated Values Introduction Structural Codes Organization of Data Nomenclature Selected Values of Standard Enthalpies of Formation Comparisons of Selected and Calculated Values for Liquids and Gases 2 Parameters for Standard Enthalpies of Formation Introduction The Pedley Method Calculations for Acyclic Hydrocarbons Calculations for Compounds Containing Functional Groups Calculations for Cyclic Compounds Comments on Values for Bond Energies Comments on Values for Bond Interactions Comments on Strain and Resonance Energies in Ring Systems 3 Comparison of Selected and Calculated Values-Identification of Suspect Data Introduction Acyclic Hydrocarbons Acyclic Oxygen Compounds Acyclic Nitrogen Compounds Acyclic Sulfur Compounds Acyclic Halogen Compounds Corrections for Ring Systems Derivatives of Benzene Concluding Remarks References A Appendix-Parameters for Standard Enthalpies of Formation Introduction Parameters for Acyclic Hydrocarbons Parameters Involving Non-Hydrocarbon Fragments in Acyclic Compounds Ring Corrections Formula Index Name Index Chemical Abstracts Service Registry Number (CASRN) Index
"The tables of data presented in this book are a great advance in comprehensive coverage and in critical evaluation, and supersede previous tables of data. This book is the most important source of thermochemical data for organic compounds now available, and users of these tables will be grateful... for the effort and care expended in their production." -Geoffrey Pilcher, Department of Chemistry, University of Manchester, England; from the Foreword
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CHOICE – Outstanding Academic Title – Award Winner
CHOICE – 2018 Outstanding Academic Title – Award Winner
Shingo Research and Professional Publication Award Winner
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