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Unlike many other references, Radiation-Chemical Processes in Solid Phase analyzes experimental data on radiolysis in terms of solid-state physics. It traces the effect exerted by media from primary processes of radiation-substance interaction to final products. The authors consider the main chemically active elementary excitations arising under irradiation of solids and discuss the mechanisms of chemical reactions induced by them. They present the general principles of solid-state and molecular physics, and cover numerous radiation-chemical processes.
Table of Contents
General Ideas of the Solid State Theory and Molecule Physics The Band Structure The Phonon Spectrum Surface Phenomena Dissociation of Excited Molecules Interaction of Radiation With a Solid Absorption of Ionizing Radiation by a Solid Short-Lived Chemically Active Elementary Excitations in a Solid Spatial Nonuniformity of Absorbed Energy Distribution Absorption of Energy in Heterogeneous Systems Primary Chemical Processes in the Irradiated Solid Ion Reactions Reactions of Electron-Excited Particles Radical Reactions Processes with Participation of Stabilized Electrons Low Temperature Radiation-Chemical Reactions General Knowledge about the Peculiarities of Low-Temperature Reactions Descriptive Methods of Low-Temperature Solid-Phase Reactions Low-Temperature Radical Reactions Experimental Data Modified Theory of Radiationless Transitions General Rate Constant of Solid Phase Chemical Reaction Radical Reactions Reactions with the Ion Transfer Comparison of Theoretical and Experimental Data Kinetic Peculiarities of Solid-Phase Radiation Chemical Reactions Radicals Annihilation in the Process of Their Accumulation under Radiation Kinetics of Radical Reactions Compensation Effect and Cage Effect Recombination Kinetics of Free Radicals in the Solid Phase Photoradiation Processes Dependence of the Radicals Concentration on the Way of Irradiation Creation of the Radicals under the Absorption of Light by Molecules Excited with Radiation to the Lower Triplet State Kinetics of the Radicals Creation under the Absorption of Light with the Stabilized Electrons The Elementary Processes of Photochain Reactions Heterogeneous Radiation-Chemical Processes Radiation Effect on Surface Properties Active Particle Reactions Radiolysis of Substances in the Absorbed State Applied Problems of Radiation Chemistry of Solids Radiation Modification of Materials Radiation-Chemical Problems of Nuclear and Radiation-Chemical Industry Radiation Processing in Microelectronics Biological and Medical Aspects of Radiation Processing Index
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CHOICE – Outstanding Academic Title – Award Winner
CHOICE – 2018 Outstanding Academic Title – Award Winner
Shingo Research and Professional Publication Award Winner
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