1st Edition

Organic Chemistry Structure and Mechanisms

Edited By Harold H. Trimm Copyright 2011
    384 Pages
    by Apple Academic Press

    384 Pages
    by Apple Academic Press

    This title includes a number of Open Access chapters.



    This book presents a range of research on important topics in the field. Of the approximately 11 million known chemical compounds, about 10 million are organic. Organic chemists are currently working to produce better polymers with specific properties, such as biodegradable plastics. The understanding of new drug structures from plants and the synthesis of improved pharmaceuticals is another area of great interest. Organic chemists are also researching the reactions that occur in living systems and understanding the molecular causes of disease.

    Mechanistic Aspects of the Isomerization of Z-Vinylic Tellurides Double Bonds in the Synthesis of Potassium Z-Vinyltrifluoroborate Salts
    The Role of Heterogeneous Chemistry of Volatile Organic Compounds: A Modeling and Laboratory Study
    Total Synthesis of the Indolizidine Alkaloid Tashiromine
    Application of Stir Bar Sorptive Extraction to Analysis of Volatile and Semivolatile Organic Chemicals of Potential Concern in Solids and Aqueous Samples from the Hanford Site
    Analogues of Amphibian Alkaloids: Total Synthesis of (5R,8S,8as)-(-)-8-Methyl-5-Pentyloctahydroindolizine (8-Epi-Indolizidine 209B) and [(1S,4R,9as)-(-)-4-Pentyloctahydro-2H-Quinolizin-1-Yl]Methanol
    An Efficient Preparation, Spectroscopic Properties, and Crystal Structure of 1,1-Bis(4-[2-(dimethylamino)ethoxy]phenyl)-2-(3-guaiazulenyl)ethylene
    Characterizing the Formation of Secondary Organic Aerosols
    Combining Two-Directional Synthesis and Tandem Reactions, Part 11: Second Generation Syntheses of (±)-Hippodamine and (±)-Epi-Hippodamine
    Accelerations in the Lactonization of Trimethyl Lock Systems Are Due to Proximity Orientation and not to Strain Effects
    Unexpected Degradation of the Bisphosphonate P-C-P Bridge Under Mild Conditions
    Synthesis of Benzo[b]fluorenone Nuclei of Stealthins
    Shape-Persistent Macrocycles with Intraannular Alkyl Groups: Some Structural Limits of Discotic Liquid Crystals with an Inverted Structure
    Part 1. Reduction of S-Alkyl-Thionocarbonates and Related Compounds in the Presence of Trialkylboranes/Air
    Part 2. Mechanistic Aspects of the Reduction of S-Alkyl-Thionocarbonates in the Presence of Triethylborane and Air
    Part 3. Triethylborane-Air: A Suitable Initiator for Intermolecular Radical Additions of S-2-Oxoalkyl-Thionocarbonates (S-Xanthates) to Olefins
    Catalytic Oxidative Cleavage of C=N Bond in the Presence of Zeolite H-NaX Supported Cu(NO3)2, as a Green Reagent
    A Divergent Asymmetric Approach to Aza-Spiropyran Derivative and (1S,8ar)-1-Hydroxyindolizidine
    Flexible Synthesis of Poison-Frog Alkaloids of the 5,8-Disubstituted Indolizidine-Class. II: Synthesis of (-)-209B, (-)-231C, (-)-233D, (-)-235B", (-)-221I, and an Epimer of 193E and Pharmacological Effects at Neuronal Nicotinic Acetylcholine Receptors
    A Novel, One-Step Palladium and Phenylsilane Activated Amidation from Allyl Ester on Solid Support
    The First Organocatalytic Carbonyl-Ene Reaction: Isomerisation-Free C-C Bond Formations Catalysed By H-Bonding Thio-Ureas
    Synthesis and Biological Evaluation of 7-O-Modified Formononetin Derivatives
    Expedient Syntheses of the N-Heterocyclic Carbene Precursor Imidazolium Salts Ipr·Hcl, Imes·Hcl and Ixy·Hcl
    Cs2CO3/[bmim]Br as an Efficient, Green, and Reusable Catalytic System for the Synthesis of N-Alkyl Derivatives of Phthalimide under Mild Conditions
    Conformational Rigidity of Silicon-Stereogenic Silanes in Asymmetric Catalysis: A Comparative Study
    Photochromism of Dihydroindolizines Part XI: Synthesis of Novel Carbon-Rich Photochromic Dihydroindolizines-Based Potential Electronic Devices
    8-Epi-Salvinorin B: Crystal Structure and Affinity at the Opioid Receptor
    Effect of Transannular Interaction on the Redox-Potentials in a Series of Bicyclic Quinones
    Three-Component One-Pot Synthesis of Novel Benzo[b]1,8-naphthyridines Catalyzed by Bismuth(III) Chloride
    The Vicinal Difluoro Motif: The Synthesis and Conformation of Erythro- and Threo- Diastereoisomers of 1,2-Difluorodiphenylethanes, 2,3-Difluorosuccinic Acids and Their Derivatives
    The In¿uence of Traf¿c and Wood Combustion on the Stable Isotopic Composition of Carbon Monoxide
    Reduction of Arenediazonium Salts by Tetrakis (Dimethylamino) Ethylene (TDAE): Efficient Formation of Products Derived from Aryl Radicals

    Biography

    Dr. Harold H. Trimm was born in 1955 in Brooklyn, New York. Dr. Trimm is the chairman of the Chemistry Department at Broome Community College in Binghamton, New York. In addition, he is an Adjunct Analytical Professor, Binghamton University, State University of New York, Binghamton, New York.



    He received his PhD in chemistry, with a minor in biology, from Clarkson University in 1981 for his work on fast reaction kinetics of biologically important molecules. He then went on to Brunel University in England for a postdoctoral research fellowship in biophysics, where he studied the molecules involved with arthritis by electroptics. He recently authored a textbook on forensic science titled Forensics the Easy Way (2005).