1st Edition

Handbook of Antioxidants Bond Dissociation Energies, Rate Constants, Activation Energies, and Enthalpies of Reactions

By Evguenii T. Denisov Copyright 1995

    Designed for scientists and engineers involved in the physical chemistry of antioxidants, the Handbook of Antioxidants contains comprehensive data on the thermodynamics and reactivity of antioxidants. It includes: bond dissociation energies of antioxidants such as phenols (O-H bonds), aromatic amines (N-H bonds), hydroxyl amines (O-H bonds), thiophenols (S-H bonds)
    o activation energies and rate constants of reactions of peroxyl radicals with antioxidants
    o rate constants of reactions of phenoxyl, aminyl, and nitroxyl radicals with RH, ROOH, phenols, thiophenols, amines and hydroxyl amines and rate constants of reactions of antioxidants with hydroperoxides and oxygen.

    1. Kinetics and Mechanism of Inhibited Oxidation of Hydrocarbons 2. Rate Constants of Elementary Steps of Chain Oxidation of Hydrocarbons 3. Bond Dissociation Energies and Rate Constants of Reaction of Phenols 4. Bond Dissociation Energies and Rate Constants of Reactions of Aromatic Amines 5. Dissociation Energies and rate Constants of Reactions of Hydroxylamines and Nitroxyl Radicals 6. Bond Dissociation Energies and Rate Constants of Reactions of Thiophenols 7. Phosphorus and Sulfur Containing Antioxidants Decomposing Hydroperoxides