This text offers authoritative contributions from nearly 200 leaders in the field and new methods to enhance catalytic reactions. "Catalysis of Organic Reactions" covers approaches for designing, modifying, and altering catalysts for improved function, performance, and stability, procedures to reduce by-product formation, and cost-effective alternatives for the hydrogenation of organic compounds. Studying the phase preference, concentration, characteristics, and recoverability of recently developed and commercial catalysts, this is an excellent guide for chemical engineers; organic, medicinal, catalytic, physical, industrial, process, inorganic, and organometallic chemists and biochemists, and surface and environmental scientists.
Table of Contents
1. 2001 Paul Rylander Plenary Lecture Immobilizing Homogeneous Catalysts for Organic Reactions 2. Polymer-Supported Catalyst for the Enantioselective Addition of Diethylzinc to Aldehydes 3. Increase of the Long-Term Stability of Chirally Modified Platinum Catalysts Used in the Enantioselective Hydrogenation of Ethyl Pyruvate 4. Application of New Metal Impregnated Knitted Silica-Fiber on Catalytic Oxidation and Hydrogenation Processes 5. Functionalised Polymer Fibres as Supports for Platinum Group Metal Catalysts 6. Nickel Bromide as a Hydrogen Transfer Catalyst 7. Small-Scale Reactors for Catalyst Evaluation and Process Optimization 8. Catalytic Hydrogenation of Citral: The Effect of Acoustic Irradiation 9. Catalytic Applications of Aluminum Isopropoxide in Organic Synthesis 10. Liquid-Phase Methylation of m-Cresol Catalyzed by Mixed Oxides Derived from Hydrotalcite Precursors: Effect of Acid-Base Features on Catalytic Performance 11. 2002 Paul Rylander Plenary Lecture Selective Heterogeneous Catalysis: Opportunities and Challenges 12. Diisopropyl Ether One-Step Generation from Acetone-Rich Feedstocks 13. Highly Selective Catalytic Oxidation of Alkylbenzenes to the Corresponding Hydroperoxides 14. Vapour Phase Oxidation of Methyl Aromatics to the Corresponding Aldehydes 15. Use of Platinum Group Metal Catalysts for the Selective Oxidation of Alcohols to Carbonyls in the Liquid Phase 16. Destruction of PTA Offgas by Catalytic Oxidation 17. 2002 Murray Raney Plenary Lecture Asymmetrically Modified Nickel Catalyst (MNi): A Heterogeneous Catalyst for the Enantio-Differentiating Hydrogenations 18. Improved Stabilities of Skeletal Cu Catalysts for Dehydrogenation and Hydrogenolysis Reactions 19. Precious Metal Promoted Raney® Ni Catalysts 20. Chemoselective Hydrogenation of Unsarurated Ketones in the Presence of Copper Catalysts 21. Activated Base Metal Hollow Spheres: The Low Density Alternative for the Fixed Bed Hydrogenation of Organic Compounds 22. Development of New Two-Step Technology for Polyols 23. Preparation and Characterization of High Activity and Low Palladium-Containing Debenzylation Catalysts 24. DuPHOS Rhodium(I) Catalysts: A Comparison of COD Versus NBD Precatalysts under Conditions of Industrial Application 25. Enhanced Regioselectivity in Batch and Continuous Hydrogenation of 1 -Phenyl-1,2-Propanedione over Modified Pt Catalysts 26. Asymmetric Catalysis Using Bisphosphite Ligands 27. Carbamate and Dicarbamate Syntheses from 28. Supported Palladium Catalysts: A Highly Active Catalytic System for CC-Coupling Reactions 29. Enantioselective Hydrogenation of Ethyl Pyruvate over Pt Colloids 30. Palladium-Catalyzed Animation of Fluorohaloarenes: A Chemoselective Synthesis of Fluoroquinolone Antibacterials 31. Catalytic Hydrogenation of Cinnamaldehyde: The Effects of Support and Supported Metal on Activity and Selectivity\ 32. Novel Synthesis of 2-Alkylhexahydropyrimidines from Nitriles and 1,3-Diamines 33. Steric and Electronic Effects in the Hydrogenation of N-Containing Heterocyclic Compounds 34. The Mechanism of Ethanol Animation over Nickel Catalysts 35. Continuous Heterogeneous Catalytic Hydrogenation of Organic Compounds in Supercritical CO2 36. Direct Reduction of C=O and C=N Bonds by Polymethylhydro-siloxane Promoted by Zn-Diamine Catalysts in Alcohol Solvents 37. Liquid-Phase Hydroxymethylation of 2-Methoxyphenol: Effect of Reaction Parameters on the Performance of Solid Acid Catalysts 38. Molecular Imprinting and Sol-Gel Encapsulated Rh Catalysts for Styrene Hydroformylation 39. The Palladium Catalyzed Synthesis of Carboxylate-Substituted Imidazolines: A New Route Using Imines, Acid Chrloride, and Carbon Monoxide 40. Assymmetric Hydroboration-Homologation: Towards the Synthesis of Gliflumide 41. Reductive Animation of Poly(vinyl Alcohol) 42. Anchored Homogeneous Catalysts: Some Studies into the Nature of the Catalytically Active Species 43. Selectivity Effects in the Hydrogenation of 4-t-butyl Phenol over Rhodium and Platinum Heterogeneous Catalysts 44. Stoichiometry and Kinetics of Gas Phase Cyclohexene Epoxidation by a Silica-Supported teAt-Butylperoxidititanium Complex 45. Dye-Labeled PNIPAM [Poly(jV-isopropylacrylamide)]-Supported Acylation Catalysts 46. Oxidation of Primary Alcohols with tert-Butylhydroperoxide in the Presence of Ruthenium Complexes 47. A Selective Process to Prepare Triacetone Amine 48. Hydrogenolysis of Ethyl Laurate to Dodecanol on Ru-Sn/Al2O3 Catalysts 49. Crotonaldehyde Hydrogenation on Ir/TiO2 50. Catalyst Deactivation in Selective Hydrogenation of p-Sitosterol to p-Sitostanol over Palladium 51. Kinetics of the Kinetics of the Hydrodechlorination of Dichlorobenzenes of Dichlorobenzenes 52. Kinetics of the Hydrodechlorination of Dichlorobenzenes 53. Effect of Reaction Parameters on the Hydrogenation of Nitrobenzene to p-Aminophenol 54. Organic Synthesis via Catalytic Distillation 55. Solvent Effects in the Use of Anchored Homogeneous Catalysts for Hydrogenation Reactions 56. A Novel Large Scale Hydrogenation Strategy of N,N-Dimethyl 4-( Acetoxy-3-Nitrophenylmethyl)-1 -H-Imidazole-1 -Sulfonamide, a Key Intermediate in the Synthesis of ABT-866 57. Catalyst Recycling in Batch and Semi-Continuous, Fixed-Bed Processes for Suzuki Cross-Coupling Reactions 58. New Chiral Modifier for Enantioselective Heterogeneous Catalytic Hydrogenation 59. Synthesis of Dimethyl Carbonate from Propylene Carbonate and Methanol over Mesoporous Solid Base Catalyst 60. Esterification of Amino Acids by Using Ionic Liquid as a Green Catalyst 61. Alkylation of Phenols by Caryophyllene on Acid Aluminosilicate Catalysts