James F. Pankow
August 21, 2019 Forthcoming
Textbook - 480 Pages
ISBN 9781439854402 - CAT# K12521
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Introduction; Thermodynamic Principles; Acid/Base Chemistry; The Electroneutrality Equation, Mass Balance Equations, and The Proton Balance Equation; Quantitative Acid/Base Calculations For Any Solution of Acids and Bases; Dependence of Values on pH and the Role of Net Strong Base; Titrations of Acids and Bases; Buffer Intensity; Chemistry of Dissolved CO2; Complexation of Metal Ions by Ligands; Simple Salts and Metal Oxides/Hydroxides/Oxyhydroxides; Solubility Behavior of Calcium Carbonate and other Divalent Metal Carbonates in Closed and Open Systems; Metal Phosphates; Which Solid Is Solubility Limiting? Examples with Fe(II) for FeCO3(s) vs. Fe(OH)2(s) using Log vs. pH Predominance Diagrams; The Kelvin Effect: The Effect of Particle Size on Dissolution and Evaporation Equilibria; Solid/Solid and Liquid/Liquid Solution Mixtures; Redox Reactions, EH, and pe; Introduction to pe-pH Diagrams: The Cases of Aqueous Chlorine, Hydrogen, and Oxygen; pe-pH Diagrams for Lead (Pb) with Negligible Dissolved CO2; pe-pH Diagrams for Lead (Pb) in the Presence of CO2 with Fixed CT, and Fixed CT and Phosphate; pe and Natural Systems; Redox Succession (Titration) in a Stratified Lake During a Period of Summer Stagnation; The Debye-Hückel Equation and Its Descendent Expressions for Activity Coefficients of Aqueous Ions; Electrical Double Layers in Aqueous Systems; Colloid Stability and Particle Double Layers;
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