Interfacial Chemistry of Rocks and Soils

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ISBN 9781420091328
Cat# 91328
 

Features

    • Provides comprehensive coverage of the thermodynamic aspects of the soil-liquid-interface system
    • Examines the roles of these processes in environmental, colloidal, and geochemistry
    • Explores agricultural, environmental, and industrial applications
    • Emphasizes the importance of chemical species

    Summary

    Knowledge of the basic interactions that take place between geological materials and different substances is the first step in understanding the effects of adsorption and other interfacial processes on the quality of rocks and soils, and on driving these processes towards a beneficial or neutral result. Interfacial Chemistry of Rocks and Soils examines the different processes at solid and liquid interfaces of soil and rock, presenting a complete analysis that emphasizes the importance of chemical species on these interactions.

    Summarizing the results and knowledge of the authors’ research in this field over several decades, this volume:

    • Explores the individual components of the studied systems: the solid, the solution, and the interface
    • Discusses the characteristics and thermodynamics of the interface
    • Illustrates the kinetic aspects of interfacial reactions
    • Examines interfacial processes in a montmorillonite model system
    • Demonstrates transformations initiated by interfacial processes
    • Studies interfacial processes of real rock and soil solution systems
    • Outlines avenues of treatment that may solve geological, soil science, and environmental problems
    • Profiles the most important analytical methods in the study of interfacial processes

    Previous books in this area typically focus on selected aspects of the subject, such as the properties of the solid phase, or the interactions of selected substances with soil/rock. This book comprehensively treats the soil-liquid-interface system. Drawn chiefly from the authors’ years of research at the Isotope Laboratory in the Department of Colloid and Environmental Chemistry at the University of Debrecen in Hungary, this book discusses chemical reactions on the surfaces/interfaces of soils and rocks; examines the role of these processes in environmental, colloid and geochemistry; and explores the effects on agricultural, environmental and industrial applications.

    Table of Contents

    Components of Soil and Rock — Solution Systems

    Solid: Soil and Rock

    Liquid: Soil and Groundwater Solutions

    Interface of Rock/Soil — Aqueous Solutions

    References

    Interfacial Processes in Geological Systems: Studies on Montmorillonite Model Substance

    Use of Montmorillonite as a Model Substance: The Important Interfacial Processes on Montmorillonite

    Cation Exchange: Outer Sphere Complexation

    Synthesis and Characterization of Cation Exchanged Montmorillonites

    Surface Acid-Base Properties of Montmorillonite

    Ion Adsorption on the External Surfaces

    Separation of Interfacial Processes of Montmorillonite

    Role of Hydrogen Ions in the Interfacial and Dissolution Processes of Montmorillonite

    Effect of Complexation Agents

    Sorption of Organic Matter on Minerals

    Transformations Initiated by Interfacial Processes of Montmorillonite

    References

    Interfacial Reactions at Rock and Soil Interfaces

    Relationship Between Interfacial Properties and Geological Origin of Bentonite Clay

    Migration of Water Soluble Substances in Rocks

    Interfacial Acid-Base Properties of Soils

    Sorption of Cyanide Anion on Soil and Sediment

    References

    Experimental Methods in Studying Interfacial Processes of Rocks and Soils

    Analysis of the Solid Phase

    Analysis of the Liquid Phase

    Study of Interfaces

    References